dbenec was half way there.
Once you have your color pallet up, double click on the
new color swatch icon next to the trash can, and create the custom color (process black with all of the colors being 100%) and name it (custom rich black) or whatever. It must be different than process black. That name is already taken by default.
Delete all of your existing colors in the color pallet that you have up now except for the registration black and your default process black. You will be saving a new set and using this as your default color pallet.
Once you have created your new black color, you must now
save that setting as a
custom color pallet. Go to the little black arrow head at the top right side of the color pallet and click the fly out window. Drag down to (SAVE SWATCH LIBRARY). It should automatically take you to the folder where all of the custom pallets will be and save. Give it a nice memorable unique name.
Now, while you still have that same document open, go up to the top menu bar to WINDOW, WORK SPACE…It maybe in another location depending on your version of Illustrator …find that …and save work space. Give that a unique name as well.
DONE.
Try it, Change the work space to DEFAULT. It will pop into the default settings. now go back to your new work space settings. All of your window placements and custom pallets should all be in place. ")
I am freelance artist/color separation specialist for printers and have a custom setting of
Registration
White, aka
Computer white, aka process white,
black, aka Process black
CUSTOM Rich Process black
CUSTOM spot color Base white
CUSTOM spot color black
CUSTOM spot color Highlight white
Those are my Illustrator default colors.