We have a 480XT which is about 2 years old now. The white starts to block up after about 10 minutes (if the ink heater has turned itself off, time to re-clean) and the yellow is not much better. The white one is normal (though ours degrades quite fast), but the yellow one is because of the print head - it loses roughly it's middle third nozzles after about 15 - 20 minutes, and then most of the rest by half an hour. A regular purge & vacuum gets it back immediately, but it's just something we live with and not uncommon when they start to age. The reason we know it's not air in the lines or anything like that is because it used to be the Magenta doing it - we swapped the head with the yellow and then the yellow did it. It was a lot easier than pulling apart the entire ink line and looking for leaks etc, which in the end we wouldn't have found anyway! The only way to fix it is a new head.
One thing to mention. Before this we had the 350GT. It was an absolute no-no to apply flush anywhere on the heads (you had to clean it with a dry stick, regularly enough for the ink to not dry). Apparently the flush would easily seep up and destroy the electronics, so the nozzles wouldn't fire. We lost a couple of heads before Oce figured out what was going on, we weren't the only ones it happened to and thankfully it was all fixed under warranty. Now I KNOW the XT models have totally different heads, and I KNOW we've been told that you can flush these ones. But I'm still hesitant, especially to expose them for a full 24 hours.
Have you been shown how to do a long purge? I assume you know you can turn off the valves at the top to turn off any inks that you don't need to purge. If you leave the valves open, then close them the moment the ink starts coming out, it continues to purge until the entire reservoir is empty (probably about 1 minute). If you open the valve again it'll immediately stop, so you don't need to purge the full reservoir, but even doing this for 15-20 seconds pushes a LOT of ink through and can unblock stubborn nozzles quite well. If you wear gloves and don't mind making a mess, while it's purging is a good time to get a stick with flush on it and really wipe the underside of the heads good - the fact that it's continuing to purge means any flush gets, um, flushed away with the ink and definitely will not get in to any electronic areas. It's probably what I'd do before I go drowning the heads.