White ink is made up of a Pigment called Titanium Dioxide (Ti02). its a much heavier pigments that others used in CMYK . in todays small picolitre size the White ink creates several problems, 1.) if the particle size of the (Ti02) is too small, you will not get the opacity and density so it will appear Gray and will require many passes(layers of white) only to get the desired effect, and if your using technology that uses a split head for white and are using only a portion of the head to do so your looking at a terrible compromise of speed. even if your using a technology with separate heads for white, you still need to run several (pass) layers for the white to achieve the desired opacity for the application. 2. todays electropiezo heads require ink to be at a certain viscosity and temperature in order to fire correctly and reliably. if the (Ti02) particle size is too large, then it will have a tendency to clog and settle creating reliability issues and still need multi layers to achive bright white opacity. AS with any inket there a good white inks, and there are not so good white inks. equally important are the printers trying to share heads for white and those that have dedicated heads for white. and also the design of the printer to effectively handle white from and ink delivery, circulation and periods of non use.