Only certain vinyls are paint receptive. I would definitely do a test first. I would also do a "tack coat/drop coat" first. A lite mist of clear, let it set up or "get tacky" then apply a regular coat. If you do it right it will not end in orange peel, it will melt into the second coat and level out. If the edges show shrinking or curling on the drop coat then it is a "no go". If you're in a heated booth wait a little longer to throw the heat on.