It sounds like there have been some spirited polycarbonate discussions here in the past. Here's my two cents worth.
The bubbles that develop later are from trapped moisture
Polycarbonate does not outgas solvent fumes as do some other plastics as they cure, as Techman mentioned in his post. Or if it does outgas solvent, it's so small an amount as to be nondetectable. However, polycarbonate
does absorb moisture, which is released as water vapor as the the plastic dries. Technically, you could call this "outgassing," but it is not how the term is commonly understood. How can this release of water vapor affect vinyl film? A technical brief from Covestro, the maker of Makrolon polycarbonate sheet, says,
“Trapped moisture within the sheet often results in bubbling of vinyl film. Pre-drying sheet leads to a surface dryness conducive to good film adhesion.”
Of course, you may not have the equipment to flash dry polycarbonate sheets for one hour at 250 degrees as Covestro recommends. Laying a sheet out overnight in a warm room may be the only option for most of us. And I suspect that those who live in a dry climate rarely experience this bubble problem.
Here's a link to the tech sheet from Covestro. Covestro, since last year, is the name of a subsidiary of Bayer, and was formerly known as Bayer MaterialScience.
http://www.covestro.com/~/media/Pro...icas/MSC115_Technical Bulletin Outgassing.pdf
An alcohol wipe removes static
Regarding cleaning, it make sense that a sheet of polycarbonate should already be clean if it has been protected by a cover sheet. But, it may also be full of static. Plastic faces cannot be spray painted successfully without removing the static, and that is the primary purpose of the alcohol/water wipe. I was taught to mix two parts water to one part alcohol and wipe with a chamois leather (not a cloth).
Isopropanol is the least toxic of the commonly used alcohols and is always my choice, but I've used "denatured" when isopropanol was not available. Denatured alcohol is ethanol that has been made poisonous so that it can't be consumed (or taxed) like whisky. Methanol, the race car fuel, is the other readily available alcohol. But it is highly toxic and I don't use it.
The Plastic Prep sold by Matthews Paint is mostly an alcohol mix.
Another anti-static technique I use when painting plastic faces is to fill a squeeze bottle full of water and squirt it all over the back of a plastic sheet just before painting. This can help you get beautifully even translucent backgrounds, even in the problem colors. I learned that trick thanks to Paul Berkshire of Peoria in the late '70s.
Brad in Kansas City